Adobe’s posted a couple of great articles on using Dreamweaver for styling your websites using CSS:
The first article (http://www.adobe.com/devnet/dreamweaver/articles/css-selectors-pt1.html) is an excellent lesson on CSS Essentials.
The second article (http://www.adobe.com/devnet/dreamweaver/articles/css-selectors-pt2.html) has some REALLY helpful information on what kind of power controls are in CSS3. WOW! CSS is getting stronger and Stronger.
And, with Dreamweaver, we don’t really have to hand-code any of it!